人才培养

欢迎品行端正、热爱科研、有协作精神的同学申请硕士和博士研究生、博士后岗位，具地球化学、分析化学、环境微生物背景者为佳。

科研项目

1） 污染物地球化学行为与气候环境效应（2026.01-2030.12），国家自然科学基金创新研究群体A类项目（42521004），主持。

2） 水环境中有机污染物界面过程研究（2013.01-2016.12），国家杰出青年基金项目（21225729），主持。

3） 污染场地中持久性有机污染物的积累效应和健康风险研究及预测模型建立（2020.01-2023.12），国家重点研发计划项目（2019YFC1804200），主持。

4） 溶解态黑碳的地球化学行为、环境效应及其在我国重要河流的循环通量（2025.01-2029.12），国家自然基金重点项目（42430710），主持。

5） 土壤中持久性有机有毒污染物的迁移转化规律及对地下水的影响（2007.01-2010.12），国家自然基金重点项目（20637030），主持。

6） 土壤中抗生素界面过程对其环境健康效应的影响及作用机制（2020.01-2024.12）, 国家自然基金国际合作重点项目（21920102002），主持。

7） 土壤复合污染多介质界面过程与生物影响机制 （2020.01-2024.12），国家自然基金重大项目课题（41991331），主持。

8） 土壤有机污染物非线性微界面行为及其分子机制（2014.01-2018.12），国家973项目课题（2014CB441103），主持。

9） 微生物胞外聚合物的还原活性及其环境效应（2018.01-2021.12），国家自然基金面上项目（21777002），主持。

10） 土壤中煤源颗粒对有机污染物的吸附、解吸研究（2011.01-2013.12），国家自然基金面上项目（21077049），主持。

11） 黏土矿物中有机胺离子与多环芳烃间的阳离子-派键作用（2008.01-2010.12），国家自然基金面上项目（20777031），主持。

12） 溶解态有机物对有机污染物在矿物表面吸附的影响（2006.01-2006.12），国家自然基金科学部主任基金（20647002），主持。

13） 有机聚合物─黏土纳米吸附材料研究（2007.01-2009.12），教育部新世纪优秀人才支持计划 （NCET-06-0453），主持。

14） 教育部留学回国人员科研启动基金（2008.09-2009.12），主持。

代表性论文

一、天然有机质、黑碳生物地球化学行为和效应

1. Wei, C., J. Liu, X. Yang, T. Huang, C. Huang, S. Tao, and D. Zhu*. 2026. Iron isotope compositions of sediment with depth-dependent iron reduction in a temperate eutrophic freshwater lake. Geochim. Cosmochim. Ac. 427: 148–155. DOI: 10.1016/j.gca.2026.07.017

2. Zhang, Z., X. Cui, S. Yin, L. Yi, S. Tao, and D. Zhu*. 2026. Aromatic nitrogen-mediated enhanced mineralization of dissolved black carbon through microbial dissimilatory iron reduction. Environ. Sci. Technol. 60: 16618–16628. DOI: 10.1021/acs.est.5c18731

3. Zhang, Z., X. Cui, C. Wei, S. Zang, S. Tao, and D. Zhu*. 2025. Contrasting photochemical behaviors between biogenic-sourced and combustion-sourced dissolved organic nitrogen. Geochim. Cosmochim. Ac. 411: 151–160. DOI: 10.1016/j.gca.2025.10.036

4. Wei, C., S. Yin, A. Kappler, S. Tao, and D. Zhu*. 2025. A new pathway for pyrite formation in low-sulfate sediments driven by mineralization of reduced organic sulfur. Fundamental Res. 5: 1607–1613. DOI: 10.1016/j.fmre.2023.08.003

5. Wei, C., S. Tao, P. G. Hatcher, and D. Zhu*. 2025. Strong depth-dependent chemical and structural characteristics of dissolved organic matter (DOM) in organic-rich sediment in a shallow temperate lake. Geochim. Cosmochim. Ac. 399: 242–256. DOI: 10.1016/j.gca.2025.05.002

6. Wei, C., H. Fu, X. Qu, S. Tao, P. G. Hatcher, and D. Zhu*. 2025. Contrasting molecular structures and photooxidation behaviors between dissolved organic sulfur released from rice straw-biochar and aerobically decomposed rice straw. Chemical Geology 671: 122494. DOI: 10.1016/j.chemgeo.2024.122494

7. Zhang, Z.^#, Cui, X.^#, X. Qu, H. Fu, S. Tao, and D. Zhu*. 2024. Revealing molecular structures of nitrogen-containing compounds in dissolved black carbon using ultrahigh-resolution mass spectrometry combined with thermodynamic calculation. Environ. Sci. Technol. 58: 11998–12007. DOI: 10.1021/acs.est.4c01829

8. Yin, S.^#, Wei, C.^#, X. Qu, H. Fu, B. Li, S. Piao, S. Tao, P. G. Hatcher, and D. Zhu*. 2024. Benzenepolycarboxylic acids as exclusive intrinsic markers to assess riverine export of dissolved black carbon. Environ. Sci. Technol. 58: 1142–1151. DOI: 10.1021/acs.est.3c05988

9. Liu, Y., M. Wang, S. Yin, L. Xie, X. Qu, H. Fu, Q. Shi, F. Zhou, F. Xu, S. Tao, and D. Zhu*. 2022. Comparing photoactivities of dissolved organic matter released from rice straw-pyrolized biochar and composted rice straw. Environ. Sci. Technol. 56: 2803–2815. DOI: 10.1021/acs.est.1c08061

10. Qu, X., H. Fu, J. Mao, Y. Ran, D. Zhang, and D. Zhu*. 2016. Chemical and structural properties of dissolved black carbon released from biochars. Carbon 96: 759–767. DOI: 10.1016/j.carbon.2015.09.106

二、重金属、有机污染物环境转化过程与机制

1. Cui, X., Z. Zhang, S. E. Lyu, K. Schmidt-Rohr, J. Mao, W. A. Mitch, S. Tao, and D. Zhu*. 2026. The soil-air interface of iron-bearing clay minerals as an overlooked hotspot for microplastics photoaging. Environ. Sci. Technol. 60: 8145–8155. DOI: 10.1021/acs.est.5c16295

2. Yi, L., W. Zhang, H. Li, Y. Lu, J. Liu, S. Tao, P. J. J. Alvarez, and D. Zhu*. 2024. Microbial dissimilatory iron reduction facilitates release and horizontal transfer of plasmid-borne antibiotic resistance genes adsorbed on hematite. Geochim. Cosmochim. Ac. 383: 70–80. DOI: 10.1016/j.gca.2024.08.005

3. Yi, L., W. Zhang, Z. Chen, H. Li, Y. Lu, S. Tao, and D. Zhu*. 2024. Products from photolysis reactions of tetracycline mediated by clay and humic substance induce contrasting expressions of target resistance genes. Environ. Sci. Technol. 58: 13950–13960. DOI: 10.1021/acs.est.4c03797

4. Wei, C., S. Tao, and D. Zhu*. 2023. New mechanism via dichlorocarbene intermediate for activated carbon-mediated reductive dechlorination of carbon tetrachloride by sulfide in aqueous solutions. Environ. Sci. Technol. 57: 15223–15231. DOI: 10.1021/acs.est.3c03333

5. Li, L., X. Wang, H. Fu, X. Qu, J. Chen, S. Tao, and D. Zhu*. 2020. Dissolved black carbon facilitates photoreduction of Hg(II) to Hg(0) and reduces mercury uptake by lettuce (Lactuca sativa L.). Environ. Sci. Technol. 54: 11137–11145. DOI: 10.1021/acs.est.0c01132

6. Zhou, X., F. Kang, X. Qu, H. Fu, P. J. J. Alvarez, S. Tao, and D. Zhu*. 2020. Role of extracellular polymeric substances in microbial reduction of arsenate to arsenite by Escherichia coli and Bacillus subtilis. Environ. Sci. Technol. 54: 6185–6193. DOI: 10.1021/acs.est.0c01186

7. Xu, L., H. Li, W. A. Mitch, S. Tao, and D. Zhu*. 2019. Enhanced phototransformation of tetracycline at smectite clay surfaces under simulated sunlight via a Lewis-base catalyzed alkalization mechanism. Environ. Sci. Technol. 53: 710–718. DOI: 10.1021/acs.est.8b06068

8. Kang, F., X. Qu, P. J. J. Alvarez, and D. Zhu*. 2017. Extracellular saccharide-mediated reduction of Au³⁺ to gold nanoparticles: New insights for heavy metals biomineralization on microbial surfaces. Environ. Sci. Technol. 51: 2776–2785. DOI: 10.1021/acs.est.6b05930

9. Kang, F., P. J. J. Alvarez, and D. Zhu*. 2014. Microbial extracellular polymeric substances reduce Ag⁺ to silver nanoparticles and antagonize bactericidal activity. Environ. Sci. Technol. 48: 316–322. DOI: 10.1021/es403796x

10. Fu, H., and D. Zhu*. 2013. Graphene oxide-facilitated reduction of nitrobenzene in sulfide-containing aqueous solutions. Environ. Sci. Technol. 47: 4204–4210. DOI: 10.1021/es304872k

三、有机污染物界面吸附行为与作用机制

1. Fu, H.#, Wang, B.^#, D. Zhu*, Z. Zhou, S. Bao, X. Qu, Y. Guo, L. Ling, S. Zheng, P. Duan, J. Mao, K. Schmidt-Rohr, S. Tao, and P. J. J. Alvarez. 2022. Mechanism for selective binding of aromatic compounds on oxygen-rich graphene nanosheets based on molecule size/polarity matching. Science Adv. 8: eabn4650. DOI: 10.1126/sciadv.abn4650

2. Ji, L., Y. Wan, S. Zheng, and D. Zhu*. 2011. Adsorption of tetracycline and sulfamethoxazole on crop residue-derived ashes: Implication for the relative importance of black carbon to soil sorption. Environ. Sci. Technol. 45: 5580–5586. DOI: 10.1021/es200483b

3. Qu, X., Y. Zhang, H. Li, S. Zheng, and D. Zhu*. 2011. Probing the specific sorption sites on montmorillonite using nitroaromatic compounds and hexafluorobenzene. Environ. Sci. Technol. 45: 2209–2216. DOI: 10.1021/es104182a

4. Ji, L., F. Liu, Z. Xu, S. Zheng*, and D. Zhu*. 2010. Adsorption of pharmaceutical antibiotics on template-synthesized ordered micro- and mesoporous carbons. Environ. Sci. Technol. 44: 3116–3122. DOI: 10.1021/es903716s

5. Ji, L., W. Chen, L. Duan, and D. Zhu*. 2009. Mechanisms for strong adsorption of tetracycline to carbon nanotubes: A comparative study using activated carbon and graphite as adsorbents. Environ. Sci. Technol. 43: 2322–2327. DOI: 10.1021/es803268b

6. Qu, X., P. Liu, and D. Zhu*. 2008. Enhanced sorption of PAHs to tetra-alkyl ammonium modified smectites via cation-π interactions. Environ. Sci. Technol. 42: 1109–1116. DOI: 10.1021/es071613f

7. Qu, X., X. Wang, and D. Zhu*. 2007. The partitioning of PAHs to egg phospholipids facilitated by copper and proton binding via cation-π interactions. Environ. Sci. Technol. 41: 8321–8327. DOI: 10.1021/es0718117

8. Chen, W., L. Duan, and D. Zhu*. 2007. Adsorption of polar and nonpolar organic chemicals to carbon nanotubes. Environ. Sci. Technol. 41: 8295–8300. DOI: 10.1021/es071230h

9. Xiao, L., X. Qu, and D. Zhu*. 2007. Biosorption of nonpolar hydrophobic organic compounds to Escherichia coli facilitated by metal and proton surface binding. Environ. Sci. Technol. 41: 2750–2755. DOI: 10.1021/es062343o

10. Chen, J., D. Zhu*, and C. Sun. 2007. Effect of heavy metals on the sorption of hydrophobic organic compounds to wood charcoal. Environ. Sci. Technol. 41: 2536–2541. DOI: 10.1021/es062113+